Melting Process Investigation of KCl Salt as a PCM by Enthalpy-Porosity Simulation Model with Temperature-dependent Physical Properties
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Abstract
Salt as a phase change material (PCM) in thermal energy storage (TES) can store solar thermal energy in the form of latent heat by experiencing a process known as the melting process. Recently, the melting process can be observed and investigated using an enthalpy-porosity simulation model. However, the use of enthalpy-porosity simulation model is still focused on constant physical properties, i.e., density and viscosity, of the PCM, and thus, the changes in the physical properties with respect to temperature during the melting process are not included in the simulation process. Therefore, this study aims to use the enthalpy-porosity simulation model with temperature-dependent physical properties of the PCM to investigate the melting process. The salt in this study is Potassium Chloride (KCl), and the computational domain is a concentric tube based on the assumption that the salt is fully contained within the computational domain. The physical properties of the KCl salt (density and viscosity) are set as functions of temperature to include the changes in the physical properties with respect to temperature during the melting process. The simulation results show that the melting process period is 450 s. In addition, the tendency of the melting rate, which is defined as the change in liquid fraction per unit time, is observed to decrease during the melting process. Compared with the constant physical properties of the KCl salt, the melting period of the KCl salt with temperature-dependent physical properties is observed to be shorter, with a deviation of 28.57%.
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G. L. Retmana, “Pemanfaatan Phase Change Material (PCM) Untuk Sistem Ventilasi Ruang Workshop Pada Kapal,” Institut Teknologi Sepuluh Nopember, Surabaya, 2020.
A. S. Fleischer, Thermal Energy Storage Using Phase Change Materials. Cham: Springer International Publishing, 2015. https://doi.org/10.1007/978-3-319-20922-7.
R. Naveenkumar et al., “Review on phase change materials for solar energy storage applications,” Environmental Science and Pollution Research, vol. 29, no. 7, pp. 9491–9532, Feb. 2022, https://doi.org/10.1007/s11356-021-17152-8.
M. Mofijur et al., “Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview,” Energies (Basel), vol. 12, no. 16, p. 3167, Aug. 2019, https://doi.org/10.3390/en12163167.
B. Yang, A. Raza, F. Bai, T. Zhang, and Z. Wang, “Microstructural evolution within mushy zone during paraffin’s melting and solidification,” Int J Heat Mass Transf, vol. 141, pp. 769–778, Oct. 2019, https://doi.org/10.1016/j.ijheatmasstransfer.2019.07.019.
P. R. Chakraborty, “Enthalpy porosity model for melting and solidification of pure-substances with large difference in phase specific heats,” International Communications in Heat and Mass Transfer, vol. 81, pp. 183–189, Feb. 2017, https://doi.org/10.1016/j.icheatmasstransfer.2016.12.023.
F. Souayfane, P. H. Biwole, and F. Fardoun, “Melting of a phase change material in presence of natural convection and radiation: A simplified model,” Appl Therm Eng, vol. 130, pp. 660–671, Feb. 2018, https://doi.org/10.1016/j.applthermaleng.2017.11.026.
S. Suhanan, M. Nadjib, P. R. Ansyah, and F. Anggara, “Simulasi Numerik Proses Pelelehan Paraffin Wax pada Unit Penyimpan Energi Termal Tipe Pipa Ganda Konsentrik,” ROTASI, vol. 19, no. 1, p. 36, Jan. 2017, https://doi.org/10.14710/rotasi.19.1.36-44.
Vikas, A. Yadav, and S. K. Soni, “Simulation of Melting Process of a Phase Change Material (PCM) using ANSYS (Fluent),” International Research Journal of Engineering and Technology, vol. 4, no. 5, pp. 3289–3294, 2017.
K. Kant, A. Shukla, A. Sharma, and P. H. Biwole, “Melting and solidification behaviour of phase change materials with cyclic heating and cooling,” J Energy Storage, vol. 15, pp. 274–282, Feb. 2018, https://doi.org/10.1016/j.est.2017.12.005.
Y. Cengel and A. Ghajar, Heat and Mass Transfer: Fundamentals and Applications, 6th Edition. McGraw-Hill, 2020.
W. D. Bennon and F. P. Incropera, “A continuum model for momentum, heat and species transport in binary solid-liquid phase change systems—I. Model formulation,” Int J Heat Mass Transf, vol. 30, no. 10, pp. 2161–2170, Oct. 1987, https://doi.org/10.1016/0017-9310(87)90094-9.
F. Li, A. Almarashi, M. Jafaryar, M. R. Hajizadeh, and Y.-M. Chu, “Melting process of nanoparticle enhanced PCM through storage cylinder incorporating fins,” Powder Technol, vol. 381, pp. 551–560, Mar. 2021, https://doi.org/10.1016/j.powtec.2020.12.026.
H. Niyas, S. Prasad, and P. Muthukumar, “Performance investigation of a lab–scale latent heat storage prototype – Numerical results,” Energy Convers Manag, vol. 135, pp. 188–199, Mar. 2017, https://doi.org/10.1016/j.enconman.2016.12.075.
G. J. Janz, F. W. Dampier, G. R. Lakshminarayanan, P. K. Lorenz, and R. P. T. Tomkins, “Molten salts: Volume 1. Electrical Conductance, Density, and Viscosity Data,” Gaithersburg, MD, 1968. https://doi.org/10.6028/NBS.NSRDS.15.
M. Kirincic, A. Trp, and K. Lenic, “Influence of natural convection during melting and solidification of paraffin in a longitudinally finned shell-and-tube latent thermal energy storage on the applicability of developed numerical models,” Renew Energy, vol. 179, pp. 1329–1344, Dec. 2021, https://doi.org/10.1016/j.renene.2021.07.083.
G. J. Janz, C. B. Allen, N. P. Bansal, R. M. Murphy, and R. P. T. Tomkins, “Physical properties data compilations relevant to energy storage :,” Gaithersburg, MD, 1979. https://doi.org/10.6028/NBS.NSRDS.61p2.
S. K. Srivastava and P. Sinha, “Analysis of thermal expansion of NaCl and KCl crystals,” Indian Journal of Physics, vol. 85, no. 8, pp. 1257–1265, Aug. 2011, https://doi.org/10.1007/s12648-011-0151-2.
D. W. Green and M. Z. Southard, Perry’s Chemical Engineers’ Handbook, 9th Edition. McGraw-Hill, 2019.
B. R. Munson, A. P. Rothmayer, T. H. Okiishi, and W. W. Huebsch, Fundamentals of Fluid Mechanics, 7th Edition. Wiley, 2012.
Z. Liu, Y. Yao, and H. Wu, “Numerical modeling for solid–liquid phase change phenomena in porous media: Shell-and-tube type latent heat thermal energy storage,” Appl Energy, vol. 112, pp. 1222–1232, Dec. 2013, https://doi.org/10.1016/j.apenergy.2013.02.022.
R. Senthil, B. M. S. Punniakodi, D. Balasubramanian, X. P. Nguyen, A. T. Hoang, and V. N. Nguyen, “Numerical investigation on melting and energy storage density enhancement of phase change material in a horizontal cylindrical container,” Int J Energy Res, vol. 46, no. 13, pp. 19138–19158, Oct. 2022, https://doi.org/10.1002/er.8228.